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If at 298K the bond energies of C--H, C-C, C = C, and H-H bonds are respectively 414, 347, 615, and 435 kJ mol-1. The value of enthalpy change for the reaction
H2C = CH2(g) + H2(g) -->H3C - CH33(g) at 298K will be:
The correct relationship between free energy change in a reaction and the corresponding equilibrium constant Kc is :
25mL of a solution of barium hydroxide on titration with 0.1 molar solution of hydrochloric acid gave a titer value of 35 mL. The molarity of barium hydroxide solution was :
The rate law for a reaction between the substances A and B is given by rate = k [A]n[B]m. On doubling the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as :
In a 0.2 molal aqueous solution of a weak acid H X, the degree of ionization is 0.3. Taking Kf for water as 1.85, the freezing point of the solution will be nearest to:
For the redox reaction
Zn(s) + cu2+ (0.1 M) --> Zn2+ (1M) + Cu(s)
taking place in a cell, E0cell is 1.10 volt. Ecell for the cell will be:
When during electrolysis of a solution of AgN03, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be
The solubility in water of a sparingly soluble salt AB2 is 1.0 x 10-5 mot U1. Its solubility product number will be
For the reaction equilibrium,
the concentrations of N2O4 and NO2 at equilibrium are 4.8 x 10-2 and 1.2 x 10-2 mol L-1 respectively. The value of Kc for the reaction is:
What volume of hydrogen gas, at 273K and 1 atm pressure will be consumed in obtaining 21.6g of elemental boron (atomic mass 10.8) from the reduction of boron trichloride by hydrogen?
Consider the reaction equilibrium
On the basis of Le-Chatelier's principle, the condition favorable for the forward reaction is
The atomic numbers of vanadium (V), chromium (Cr), manganese (Mn) and iron (Fe) are respectively 23, 24, 25 and 26. Which one of these may be expected to have the highest second ionization enthalpy?
In the anion HCOO- the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?
Which one of the following groupings represents a collection of isoelectronic species?
(At. numbers : Cs-55, Br-35)
According to the kinetic theory of gases in an ideal gas, between two successive collisions a gas molecule travels:
Graphite is a soft solid lubricant extremely difficult to melt. The reason for this anamalous behavior is that :